There are Iron Age Celtic scabbards described as "all metal", usually iron, but sometimes bronze or iron and bronze. I don't know whether they're really all-iron, or iron-covered wooden cores, or lined.
19th century British iron scabbards I've seen had (or were supposed to have) wooden liners to keep the edge away from the iron. The problem is that the lining strips would wear, and not do their job properly. In 1880, they started to do scabbards with a solid wooden liner (rather than strips), so the late scabbards are basically iron/steel-covered wooden scabbards.
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